Alexander Hinz

short CV

2018 to date

2015 – 2018

2012 – 2015

2011 – 2012

Habilitation with Prof. F. Breher, KIT

Post-doc with Prof. J. M. Goicoechea, University of Oxford

PhD with Prof. A. Schulz, Universität Rostock

Diplom with Prof. M. Köckerling, Universität Rostock


Publications

[45]    Synthesis and thermal decomposition of heavy tetrylenes bearing N‐Aminocarbazolyl substituents”. A. Hinz, Chem. Eur. J. 2019, DOI 10.1002/chem.201901573.

[44]    Increasing steric demand through flexible bulk – primary phosphanes with 2,6-bis(benzhydryl) phenyl backbones”. J. Bresien, J. M. Goicoechea, A. Hinz, M. T. Scharnhölz, A. Schulz, T. Suhrbier, A. Villinger, Dalton Trans. 2019, DOI 10.1039/C9DT00399A.

[43]    Metastable phosphorus neutral monoradical: a key intermediate in the bicyclic cage formation”. X. Chen, A. Hinz, J. R. Harmer, Z. Li, Dalton Trans. 2019, DOI 10.1039/C8DT04842H.

[42]    Pseudo-one-coordinate Tetrylenium Salts Bearing a Bulky Carbazolyl Substituent”. A. Hinz, Chem. Eur. J. 2019, DOI 10.1002/chem.201806346.

[41]    A general synthesis of phosphorus- and arsenic-containing analogues of the thio- and seleno-cyanate anions”. F. Tambornino, A. Hinz, R. Köppe, J. M. Goicoechea, Angew. Chem. 2018, 130, 8362–8366; Angew. Chem. Int. Ed. 2018, 57, 8230–8234.

[40]    The heterocubane [TerSnAs]4”. A. Hinz, J. M. Goicoechea, Dalton Trans. 2018, 8879–8883.

[39]     Highlight: “An Anionic Aluminium Nucleophile”. A. Hinz, F. Breher, Angew. Chem. 2018, 130, 8954–8956; Angew. Chem. Int. Ed. 2018, 57, 8818–8820.

[38]    Intercepting a Transient Phosphino-Arsinidene”. A. Hinz, M. M. Hansmann, G. Bertrand, J. M. Goicoechea, Chem. Eur. J. 2018, 24, 9514–9519.

[37]    Limitations of Steric Bulk: Towards Phospha-Stannyne and Phospha-Germyne”. A. Hinz, J. M. Goicoechea, Chem. Eur. J. 2018, 24, 7358–7363.

[36]    As-N and As-N-P Cage Compounds Generated by [2+2] Addition of Diazenes and Diphosphenes to Diarsadiazanediyls”. J. Bresien, A. Hinz, A. Schulz, A. Villinger, Eur. J. Inorg. Chem. 2018, 1679–1682.

[35]    Trapping of Transient, Heavy Pnictogen-Centred Biradicals”. J. Bresien, A. Hinz, A. Schulz, A. Villinger, Dalton Trans. 2018, 47, 4433–4436.

[34]    An isolable phosphaethynolato-borane and its reactivity”. D. W. N. Wilson, A. Hinz, J. M. Goicoechea, Angew. Chem. 2018, 130, 2210–2215; Angew. Chem. Int. Ed. 2018, 57, 2188–2193.

[33]    Biradicaloid and Zwitterion Reactivity of Dicarbondiphosphide Stabilized with N-Heterocyclic Carbenes”. Z. Li, Y. Hou, Y. Li, A. Hinz, X. Chen, Chem. Eur. J. 2018, 24, 4849–4855. Highlighted with a Cover Feature.

[32]    Synthesis and reactivity of nickel-stabilised µ222-P2, As2 and PAs units”. G. Hierlmeier, A. Hinz, R. Wolf, J. M. Goicoechea, Angew. Chem. 2018, 130, 439–444; Angew. Chem. Int. Ed. 2018, 57, 431–436.

[31]    L3C3P3: Tricarbontriphosphide Cage Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes”. Z. Li, Y. Hou, Y. Li, A. Hinz, J. R. Harmer, C.-Y. Su, G. Bertrand, H. Grützmacher, Angew. Chem. 2018, 130, 204–208; Angew. Chem. Int. Ed. 2018, 57, 198–202.

[30]    On the Borderline Between Discrete Complex Ions and Extended Structures: An Unprecedented Large Undecanuclear Azido-cuprate(II) Anion in Crystals of (PPN)2[Cu11(N3)24(C2H5OH)2]”. A. Hinz, M. Köckerling, ChemistrySelect 2017, 2, 9654–9657.

[29]   Dichloro-cycloazatriphosphane – the missing link between N2P2 and P4 ring systems in the systematic development of NP chemistry”. J. Bresien, A. Hinz, A. Schulz, T. Suhrbier, M. Thomas, A. Villinger, Chem. Eur. J. 2017, 23, 14738–14742.

[28]   N-Heterocyclic Carbene-Stabilised Arsinidene (AsH)”. A. Doddi, M. Weinhart, A. Hinz, D. Bockfeld, J. M. Goicoechea, M. Scheer, M. Tamm, Chem. Commun. 2017, 53, 6069–6072.

[27]   HPCO – A Phosphorus-Containing Analogue of Isocyanic Acid”. A. Hinz, R. Labbow, C. Rennick, A. Schulz, J. M. Goicoechea, Angew. Chem. 2017, 129, 3969–3973; A. Hinz, R. Labbow, C. Rennick, A. Schulz, J. M. Goicoechea, Angew. Chem. Int. Ed. 2017, 56, 3911–3915.

[26]    Synthesis, Properties, and Structures of Low-melting Tetraisocyanato-cobaltate(II)-based Ionic Liquids”. T. Peppel, A. Hinz, P. Thiele, M. Geppert-Rybczyńska, J. K. Lehmann, M. Köckerling, Eur. J. Inorg. Chem. 2017, 2017, 885–893.

[25]    A Monoanionic Arsenide Source. Decarbonylation of the 2-Arsaethynolate Anion on Reaction with Bulky Stannylenes“. A. Hinz, J. M. Goicoechea, Angew. Chem. 2016, 128, 15741–15746; A. Hinz, J. M. Goicoechea, Angew. Chem. Int. Ed. 2016, 55, 15515–15519.

[24]    Metal-free Activation of Hydrogen, Carbon Dioxide and Ammonia by Open Shell Singlet Biradicaloid [P(µ-NTer)]2“. A. Hinz, A. Schulz, A. Villinger, Angew. Chem. 2016, 128, 12402–12406; Angew. Chem. Int. Ed. 2016, 55, 12214–12218.

[23]    Synthesis Of A Molecule With Four Different Adjacent Pnictogens. A. Hinz, A. Schulz, A. Villinger, Chem. Eur. J. 2016, 22, 12266–12269. Highlighted in C&EN 2016, 94 (30), 11.

[22]    Synthesis of a Silylated Phosphorus Biradicaloid and Its Utilization in the Activation of Small Molecules“. A. Hinz, A. Schulz, A. Villinger, Eur. J. Inorg. Chem. 2016, 22, 3611–3619.

[21]    Minimalistic ditopic ligands: S,N-donor-substituted alkyne as effective intermetallic conjugation linker“. W. W. Seidel, J. Rüger, C. Timmermann, A. Villinger, A. Hinz, D. Hollmann, Chem. Eur. J. 2016, 22, 11191–11195.

[20]    On the Behaviour of Biradicaloid [P(µ-NTer)]2 Towards Lewis Acids and Bases“. A. Hinz, A. Schulz, A. Villinger, Chem. Commun. 2016, 52, 6328–6331.

[19]    The 2-arsaethynolate anion. Synthesis and reactivity towards heteroallenes“. A. Hinz, J. Goicoechea, Angew. Chem. 2016, 128, 8678–8683; Angew. Chem. Int. Ed. 2016, 55, 8536–8541. Frontispiece in Angew. Chem./Angew. Chem. Int. Ed. 2016. Highlighted in C&EN 2016, 94 (18), 11, and in Nachrichten aus der Chemie 2016, 64 (10), 943;.

[18]    Synthesis of Heavy Dipnicta-diphosphacyclobutanes [ClE(µ-PTer)]2“. A. Hinz, A. Schulz, A. Villinger, Inorg. Chem. 2016, 55, 3692–3699.

[17]    Activation of Small Molecules by Biradicaloids“. A. Hinz, Axel Schulz, Phosphorus Sulfur Silicon Relat. Elem. 2016, 191, 578–581.

[16]    A Zwitterionic and a Biradicaloid Cyclopentane Derivative“. A. Hinz, A. Schulz, A. Villinger, Chem. Sci. 2016, 7, 745–751.

[15]    Reduction of dichloro(diaza-phospha)stibanes – isolation of a donor-stabilized distibenium dication“. A. Hinz, J. Rothe, A. Schulz, A. Villinger, Dalton Trans. 2016, 45, 6044–6052.

[14]    Tunable Formation of Cyclopentane-1,3-diyls by 1,1-Insertion of Isonitriles into Diphosphadiazanediyl“. A. Hinz, A. Schulz, A. Villinger, J. Am. Chem. Soc. 2015, 137, 9953–9962.

[13]    Accessing heavy allyl-analogous [(TerN)2E] (E = Sb, Bi) salts and their reactivity towards ECl3“. A. Hinz, A. Schulz, A. Villinger, Chem. Commun. 2015, 51, 11437–11440.

[12]    Synthesis and Structure of Tritylium Salts“. A. Hinz, R. Labbow, F. Reiß, A. Schulz, K. Sievert, A. Villinger, Struct. Chem. 2015, 26, 1641–1650.

[11]    Cyclic Group 15 Radical Cations“. A. Brückner, A. Hinz, J. B. Priebe, A. Schulz, A. Villinger, Angew. Chem. 2015, 127, 7534–7538; A. Brückner, A. Hinz, J. B. Priebe, A. Schulz, A. Villinger, Angew. Chem. Int. Ed. 2015, 54, 7426–7430.

[10]    A New Mixed-Valent Copper Cyanido complex and a new Copper(II) Acetato complex, prepared with an Ionic Liquid“. A. Hinz, M. Köckerling, Z. Anorg. Allg. Chem. 2015, 641, 1347–1351.

[9]      Spontaneous Formation of an η4-Ethylene Bis(carbene) Ligand by Alkyne Coupling at Re(III)“. S. Kleinschmidt, D. Schallenberg, K. Helmdach, A. Hinz, A. Villinger, W. W. Seidel, Organometallics 2015, 34, 1091–1097.

[8]      Cyclo-Pnicta-triazanes: Biradicaloids – or Zwitterions?“. A. Hinz, A. Schulz, A. Villinger, J.-M. Wolter, J. Am. Chem. Soc. 2015, 137, 3975–3980.

[7]      Stable Heterocyclopentane-1,3-diyls“. A. Hinz, A. Schulz, A. Villinger, Angew. Chem. 2015, 127, 2815–2819; A. Hinz, A. Schulz, A. Villinger, Angew. Chem. Int. Ed. 2015, 54, 2776–2779.

[6]      P-P sigma-Bond Activation by Gold(I) Coordination“. A. Hinz, A. Schulz, A. Villinger, Chem. Commun. 2015, 51, 1363–1366.

[5]      A Mixed Arsenic-Phosphorus Centered Biradicaloid“. A. Hinz, A. Schulz, A. Villinger, Angew. Chem. 2014, 127, 678–682; A. Hinz, A. Schulz, A. Villinger, Angew. Chem. Int. Ed. 2014, 54, 668–672.

[4]      A New Class of Azadipnictiridines Generated by an Unusual Rearrangement Reaction“. A. Hinz, A. Schulz, W. W. Seidel, A. Villinger, Inorg. Chem. 2014, 53, 11682–11690.

[3]      Activation of Small Molecules by Phosphorus Biradicaloids“. A. Hinz, R. Kuzora, U. Rosenthal, A. Schulz, A. Villinger, Chem. Eur. J. 2014, 2, 14659–14673.

[2]      New P-N cage compounds generated by small-molecule activation“. A. Hinz, A. Schulz, A. Villinger, Chem. Eur. J. 2014, 20, 3913–3916.

[1]      Salts with the [NiBr3(L)] complex anion (L = 1-methylimidazole, 1-methylbenzimidazole, quinoline, and triphenylphosphane) and low melting points: A comparative study“. T. Peppel, A. Hinz, M. Köckerling, Polyhedron 2013, 52, 482–490.