Affiliated with the Institute of Inorganic Chemistry at KIT

ORCID: https://orcid.org/0000-0002-7831-1410

Researchgate: Alexander Hinz

[43]     “Metastable phosphorus neutral monoradical: a key intermediate in the bicyclic cage formation”. X. Chen, A. Hinz, J. R. Harmer, Z. Li, Dalton Trans. 2019, DOI 10.1039/C8DT04842H.

[42]     “Pseudo-one-coordinate Tetrylenium Salts Bearing a Bulky Carbazolyl Substituent”. A. Hinz, Chem. Eur. J. 2019, DOI 10.1002/chem.201806346.

[41]     “A general synthesis of phosphorus- and arsenic-containing analogues of the thio- and seleno-cyanate anions”. F. Tambornino, A. Hinz, R. Köppe, J. M. Goicoechea, Angew. Chem. 2018, 130, 8362–8366; Angew. Chem. Int. Ed. 2018, 57, 8230–8234.

[40]     “The heterocubane [TerSnAs]₄”. A. Hinz, J. M. Goicoechea, Dalton Trans. 2018, 8879–8883.

[39]     Highlight: “An Anionic Aluminium Nucleophile”. A. Hinz, F. Breher, Angew. Chem. 2018, 130, 8954–8956; Angew. Chem. Int. Ed. 2018, 57, 8818–8820.

[38]     “Intercepting a Transient Phosphino-Arsinidene”. A. Hinz, M. M. Hansmann, G. Bertrand, J. M. Goicoechea, Chem. Eur. J. 2018, 24, 9514–9519.

[37]     “Limitations of Steric Bulk: Towards Phospha-Stannyne and Phospha-Germyne”. A. Hinz, J. M. Goicoechea, Chem. Eur. J. 2018, 24, 7358–7363.

[36]     “As-N and As-N-P Cage Compounds Generated by [2+2] Addition of Diazenes and Diphosphenes to Diarsadiazanediyls”. J. Bresien, A. Hinz, A. Schulz, A. Villinger, Eur. J. Inorg. Chem. 2018, 1679–1682.

[35]     “Trapping of Transient, Heavy Pnictogen-Centred Biradicals”. J. Bresien, A. Hinz, A. Schulz, A. Villinger, Dalton Trans. 2018, 47, 4433–4436.

[34]     “An isolable phosphaethynolato-borane and its reactivity”. D. W. N. Wilson, A. Hinz, J. M. Goicoechea, Angew. Chem. 2018, 130, 2210–2215; Angew. Chem. Int. Ed. 2018, 57, 2188–2193.

[33]     “Biradicaloid and Zwitterion Reactivity of Dicarbondiphosphide Stabilized with N-Heterocyclic Carbenes”. Z. Li, Y. Hou, Y. Li, A. Hinz, X. Chen, Chem. Eur. J. 2018, 24, 4849–4855. Highlighted with a Cover Feature.

[32]     “Synthesis and reactivity of nickel-stabilised µ²:η²,η²-P₂, As₂ and PAs units”. G. Hierlmeier, A. Hinz, R. Wolf, J. M. Goicoechea, Angew. Chem. 2018, 130, 439–444; Angew. Chem. Int. Ed. 2018, 57, 431–436.

[31]     “L₃C₃P₃: Tricarbontriphosphide Cage Radicals and Cations Stabilized by Cyclic (alkyl)(amino)carbenes”. Z. Li, Y. Hou, Y. Li, A. Hinz, J. R. Harmer, C.-Y. Su, G. Bertrand, H. Grützmacher, Angew. Chem. 2018, 130, 204–208; Angew. Chem. Int. Ed. 2018, 57, 198–202.

[30]     “On the Borderline Between Discrete Complex Ions and Extended Structures: An Unprecedented Large Undecanuclear Azido-cuprate(II) Anion in Crystals of (PPN)₂[Cu₁₁(N₃)₂₄(C₂H₅OH)₂]”. A. Hinz, M. Köckerling, ChemistrySelect 2017, 2, 9654–9657.

[29]    “Dichloro-cycloazatriphosphane – the missing link between N₂P₂ and P₄ ring systems in the systematic development of NP chemistry”. J. Bresien, A. Hinz, A. Schulz, T. Suhrbier, M. Thomas, A. Villinger, Chem. Eur. J. 2017, 23, 14738–14742.

[28]    “N-Heterocyclic Carbene-Stabilised Arsinidene (AsH)”. A. Doddi, M. Weinhart, A. Hinz, D. Bockfeld, J. M. Goicoechea, M. Scheer, M. Tamm, Chem. Commun. 2017, 53, 6069–6072.

[27]    “HPCO – A Phosphorus-Containing Analogue of Isocyanic Acid”. A. Hinz, R. Labbow, C. Rennick, A. Schulz, J. M. Goicoechea, Angew. Chem. 2017, 129, 3969–3973; A. Hinz, R. Labbow, C. Rennick, A. Schulz, J. M. Goicoechea, Angew. Chem. Int. Ed. 2017, 56, 3911–3915.

[26]     “Synthesis, Properties, and Structures of Low-melting Tetraisocyanato-cobaltate(II)-based Ionic Liquids”. T. Peppel, A. Hinz, P. Thiele, M. Geppert-Rybczyńska, J. K. Lehmann, M. Köckerling, Eur. J. Inorg. Chem. 2017, 2017, 885–893.

[25]     “A Monoanionic Arsenide Source. Decarbonylation of the 2-Arsaethynolate Anion on Reaction with Bulky Stannylenes“. A. Hinz, J. M. Goicoechea, Angew. Chem. 2016, 128, 15741–15746; A. Hinz, J. M. Goicoechea, Angew. Chem. Int. Ed. 2016, 55, 15515–15519.

[24]     “Metal-free Activation of Hydrogen, Carbon Dioxide and Ammonia by Open Shell Singlet Biradicaloid [P(µ-NTer)]₂“. A. Hinz, A. Schulz, A. Villinger, Angew. Chem. 2016, 128, 12402–12406; Angew. Chem. Int. Ed. 2016, 55, 12214–12218.

[23]     “Synthesis Of A Molecule With Four Different Adjacent Pnictogens“. A. Hinz, A. Schulz, A. Villinger, Chem. Eur. J. 2016, 22, 12266–12269. Highlighted in C&EN 2016, 94 (30), 11.

[22]     “Synthesis of a Silylated Phosphorus Biradicaloid and Its Utilization in the Activation of Small Molecules“. A. Hinz, A. Schulz, A. Villinger, Eur. J. Inorg. Chem. 2016, 22, 3611–3619.

[21]     “Minimalistic ditopic ligands: S,N-donor-substituted alkyne as effective intermetallic conjugation linker“. W. W. Seidel, J. Rüger, C. Timmermann, A. Villinger, A. Hinz, D. Hollmann, Chem. Eur. J. 2016, 22, 11191–11195.

[20]     “On the Behaviour of Biradicaloid [P(µ-NTer)]₂ Towards Lewis Acids and Bases“. A. Hinz, A. Schulz, A. Villinger, Chem. Commun. 2016, 52, 6328–6331.

[19]     “The 2-arsaethynolate anion. Synthesis and reactivity towards heteroallenes“. A. Hinz, J. Goicoechea, Angew. Chem. 2016, 128, 8678–8683; Angew. Chem. Int. Ed. 2016, 55, 8536–8541. Frontispiece in Angew. Chem./Angew. Chem. Int. Ed. 2016. Highlighted in C&EN 2016, 94 (18), 11, and in Nachrichten aus der Chemie 2016, 64 (10), 943;.

[18]     “Synthesis of Heavy Dipnicta-diphosphacyclobutanes [ClE(µ-PTer)]₂“. A. Hinz, A. Schulz, A. Villinger, Inorg. Chem. 2016, 55, 3692–3699.

[17]     “Activation of Small Molecules by Biradicaloids“. A. Hinz, Axel Schulz, Phosphorus Sulfur Silicon Relat. Elem. 2016, 191, 578–581.

[16]     “A Zwitterionic and a Biradicaloid Cyclopentane Derivative“. A. Hinz, A. Schulz, A. Villinger, Chem. Sci. 2016, 7, 745–751.

[15]     “Reduction of dichloro(diaza-phospha)stibanes – isolation of a donor-stabilized distibenium dication“. A. Hinz, J. Rothe, A. Schulz, A. Villinger, Dalton Trans. 2016, 45, 6044–6052.

[14]     “Tunable Formation of Cyclopentane-1,3-diyls by 1,1-Insertion of Isonitriles into Diphosphadiazanediyl“. A. Hinz, A. Schulz, A. Villinger, J. Am. Chem. Soc. 2015, 137, 9953–9962.

[13]     “Accessing heavy allyl-analogous [(TerN)₂E]^– (E = Sb, Bi) salts and their reactivity towards ECl₃“. A. Hinz, A. Schulz, A. Villinger, Chem. Commun. 2015, 51, 11437–11440.

[12]     “Synthesis and Structure of Tritylium Salts“. A. Hinz, R. Labbow, F. Reiß, A. Schulz, K. Sievert, A. Villinger, Struct. Chem. 2015, 26, 1641–1650.

[11]     “Cyclic Group 15 Radical Cations“. A. Brückner, A. Hinz, J. B. Priebe, A. Schulz, A. Villinger, Angew. Chem. 2015, 127, 7534–7538; A. Brückner, A. Hinz, J. B. Priebe, A. Schulz, A. Villinger, Angew. Chem. Int. Ed. 2015, 54, 7426–7430.

[10]     “A New Mixed-Valent Copper Cyanido complex and a new Copper(II) Acetato complex, prepared with an Ionic Liquid“. A. Hinz, M. Köckerling, Z. Anorg. Allg. Chem. 2015, 641, 1347–1351.

[9]       “Spontaneous Formation of an η⁴-Ethylene Bis(carbene) Ligand by Alkyne Coupling at Re(III)“. S. Kleinschmidt, D. Schallenberg, K. Helmdach, A. Hinz, A. Villinger, W. W. Seidel, Organometallics 2015, 34, 1091–1097.

[8]       “Cyclo-Pnicta-triazanes: Biradicaloids – or Zwitterions?“. A. Hinz, A. Schulz, A. Villinger, J.-M. Wolter, J. Am. Chem. Soc. 2015, 137, 3975–3980.

[7]       “Stable Heterocyclopentane-1,3-diyls“. A. Hinz, A. Schulz, A. Villinger, Angew. Chem. 2015, 127, 2815–2819; A. Hinz, A. Schulz, A. Villinger, Angew. Chem. Int. Ed. 2015, 54, 2776–2779.

[6]       “P-P sigma-Bond Activation by Gold(I) Coordination“. A. Hinz, A. Schulz, A. Villinger, Chem. Commun. 2015, 51, 1363–1366.

[5]       “A Mixed Arsenic-Phosphorus Centered Biradicaloid“. A. Hinz, A. Schulz, A. Villinger, Angew. Chem. 2014, 127, 678–682; A. Hinz, A. Schulz, A. Villinger, Angew. Chem. Int. Ed. 2014, 54, 668–672.

[4]       “A New Class of Azadipnictiridines Generated by an Unusual Rearrangement Reaction“. A. Hinz, A. Schulz, W. W. Seidel, A. Villinger, Inorg. Chem. 2014, 53, 11682–11690.

[3]       “Activation of Small Molecules by Phosphorus Biradicaloids“. A. Hinz, R. Kuzora, U. Rosenthal, A. Schulz, A. Villinger, Chem. Eur. J. 2014, 2, 14659–14673.

[2]       “New P-N cage compounds generated by small-molecule activation“. A. Hinz, A. Schulz, A. Villinger, Chem. Eur. J. 2014, 20, 3913–3916.

[1]       “Salts with the [NiBr₃(L)]^– complex anion (L = 1-methylimidazole, 1-methylbenzimidazole, quinoline, and triphenylphosphane) and low melting points: A comparative study“. T. Peppel, A. Hinz, M. Köckerling, Polyhedron 2013, 52, 482–490.